What quide you need? Just pick transport with enough turrets, stay at locations where NPC transports spawns and shot em to get cargo and then sell it.
Pretty good place is Omega 3 where you can get HFuel and sell it to Freeport 1 then.
There is an art to it. The galileo spot is good, but you will find yourself having to dock on Denver, unmount your ID, get bribes for Ageira and Universal (Galileo golds mostly libertonian npcs) bribe, then remount your Junker ID.
Other spots are in the Omegas, where you can sell Hfuel on the Freeport nearby.
My favorite spot was Sigma 13 near the gate. Niobium, gold, High Temp alloy, Superalloy- all sells off in Frankfurt and Munich.
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Sigma-13 > Honshu, or Sigma-13 > Frankfurt; Gold, Super Alloys, Cryocubes, Gold, Temp Alloys, Robotics, H-fuel, Cigars, Iridium.
Munich > Berlin : Engine Components, Quantum Multi..blah?, Platinum, H-fuel, Cigars.
Good cryo pirating can be near saint quento station at picardy ( they come every 30 seconds with 80k cubes and alloys ) ( Best to do it with junker ID, cuz zoners are.. well not welcomed?)
There are other places, but Kusari > Rhienland are the best.
I am doiing it when i am bored...just made 16 mills in 10 minute in O3 outside FP1.And spoked 3 traders...the place was filled with nanos/bats/remains...everithing you can posibly imagine
Galileo (the turn 15k from Cassini hole) was awesome back then Cassini didn't suck as hard as it does now in 4.86. In 4.85 with a bunch of buddies, I did a lot of cargo piracy there for High temp alloys, diamonds, pretty neat and much stuff. Now it's just not the same, haven't been npc cargo pirating since then.
Is their an up to date area anyone can think of to do some good, NPC pirating all seems to be the same really where ever I go. Its getting quite bland.